Abstract
Reactions of vinylidenecyclopropanes with diaryl diselenide catalyzed by iodosobenzene
diacetate produced the corresponding addition products 4 in moderate to good yields under mild conditions. The further transformation of 4 to the corresponding methylenecyclopropanes 5 has been disclosed in the presence of hydrogen peroxide (H2 O2 ) in toluene.
Key words
arylvinylidenecyclopropanes - diaryl diselenide - iodosobenzene diacetate - methylenecyclopropanes
- addition reaction
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The crystal data of 4a has been deposited in CCDC with number 249984. Empirical formula: C35 H28 Se2 ; formula weight: 606.49; crystal color, habit: colourless, prismatic; crystal system:
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General Procedure.
2 2
